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Keywords = films

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23 pages, 1978 KiB  
Article
Impact of H-Related Chemical Bonds on Physical Properties of SiNx:H Films Deposited via Plasma-Enhanced Chemical Vapor Deposition
by Jianping Ning, Zhen Tang, Lunqian Chen, Bowen Li, Qidi Wu, Yue Sun and Dayu Zhou
Electronics 2024, 13(14), 2779; https://doi.org/10.3390/electronics13142779 (registering DOI) - 15 Jul 2024
Viewed by 104
Abstract
SiNx:H film deposition via plasma-enhanced chemical vapor deposition has been widely used in semiconductor devices. However, the relationship between the chemical bonds and the physical and chemical properties has rarely been studied for films deposited using tools in terms of the [...] Read more.
SiNx:H film deposition via plasma-enhanced chemical vapor deposition has been widely used in semiconductor devices. However, the relationship between the chemical bonds and the physical and chemical properties has rarely been studied for films deposited using tools in terms of the actual volume production. In this study, we investigated the effects of the deposition conditions on the H-related chemical bonding, physical and chemical properties, yield, and quality of SiNx:H films used as passivation layers at the 28 nm technology node. The radiofrequency (RF) power, electrode plate spacing, temperature, chamber pressure, and SiH4:NH3 gas flow ratio were selected as the deposition parameters. The results show a clear relationship between the H-related chemical bonds and the examined film properties. The difference in the refractive index (RI) and breakdown field (EB) of the SiNx:H films is mainly attributed to the change in the Si–H:N–H ratio. As the Si–H:N–H ratio increased, the RI and EB showed linear growth and exponential downward trends, respectively. In addition, compared with the Si–H:N–H ratio, the total Si–H and N–H contents had a greater impact on the wet etching rates of the SiNx:H films, but the stress was not entirely dependent on the total Si–H and N–H contents. Notably, excessive electrode plate spacing can lead to a significant undesired increase in the non-uniformity and surface roughness of SiNx:H films. This study provides industry-level processing guidance for the development of advanced silicon nitride film deposition technology. Full article
(This article belongs to the Special Issue New Insights into Memory/Storage Circuit, Architecture, and System)
38 pages, 2753 KiB  
Review
Recent Advances in Poly(vinyl Alcohol)-Based Hydrogels
by Maria Bercea
Polymers 2024, 16(14), 2021; https://doi.org/10.3390/polym16142021 (registering DOI) - 15 Jul 2024
Viewed by 68
Abstract
Poly(vinyl alcohol) (PVA) is a versatile synthetic polymer, used for the design of hydrogels, porous membranes and films. Its solubility in water, film- and hydrogel-forming capabilities, non-toxicity, crystallinity and excellent mechanical properties, chemical inertness and stability towards biological fluids, superior oxygen and gas [...] Read more.
Poly(vinyl alcohol) (PVA) is a versatile synthetic polymer, used for the design of hydrogels, porous membranes and films. Its solubility in water, film- and hydrogel-forming capabilities, non-toxicity, crystallinity and excellent mechanical properties, chemical inertness and stability towards biological fluids, superior oxygen and gas barrier properties, good printability and availability (relatively low production cost) are the main aspects that make PVA suitable for a variety of applications, from biomedical and pharmaceutical uses to sensing devices, packaging materials or wastewater treatment. However, pure PVA materials present low stability in water, limited flexibility and poor biocompatibility and biodegradability, which restrict its use alone in various applications. PVA mixed with other synthetic polymers or biomolecules (polysaccharides, proteins, peptides, amino acids etc.), as well as with inorganic/organic compounds, generates a wide variety of materials in which PVA’s shortcomings are considerably improved, and new functionalities are obtained. Also, PVA’s chemical transformation brings new features and opens the door for new and unexpected uses. The present review is focused on recent advances in PVA-based hydrogels. Full article
(This article belongs to the Special Issue Advances in Poly(Vinyl Alcohol)-Based Materials)
12 pages, 2192 KiB  
Article
Mechanism Study on the Effect of Surface Electrical Property on Microbial Membrane Formation Efficiency of TiO2-SiC Composite Filler in Recirculating Aquaculture System
by Jiaxin Li, Ze Hong, Jingying Ouyang, Han Zheng and Ying Liu
Materials 2024, 17(14), 3501; https://doi.org/10.3390/ma17143501 (registering DOI) - 15 Jul 2024
Viewed by 91
Abstract
Recirculating aquaculture systems (RASs) offer significant advantages in aquaculture by markedly decreasing water usage and increasing culture density. A vital component within a RAS is the filler material, which serves as a surface for microbial colonization. Effective microbial treatment is crucial for the [...] Read more.
Recirculating aquaculture systems (RASs) offer significant advantages in aquaculture by markedly decreasing water usage and increasing culture density. A vital component within a RAS is the filler material, which serves as a surface for microbial colonization. Effective microbial treatment is crucial for the efficient operation of a RAS as it assists in purifying the wastewater generated within the system. Nevertheless, traditional fillers often show low efficiency in biofilm formation. The commercial silicon carbide used in this study is a foam ceramic filter with a density of about 0.4–0.55 g/cm3, a number of holes of about 10, and a through porosity of 80.9%, with a diameter of about 5 cm. This research investigates the utilization of a titanium dioxide–silicon carbide (TiO2-SiC) composite filler to improve the purification efficiency of ammonia nitrogen and chemical oxygen demand (COD) in aquaculture wastewater. The study involved the application of titanium dioxide films onto the surface of silicon carbide to produce the composite filler. This method takes advantage of the dipole interaction between titanium dioxide and microorganisms, which enhances biofilm culturing efficiency on the silicon carbide surface. The performance of three different fillers was assessed for their ability to purify aquaculture wastewater. Results showed that the TiO2-SiC composite filler was 1.67 times more effective in removing COD and 1.07 times more effective in removing ammonia nitrogen compared to using silicon carbide alone. These results demonstrate that the incorporation of a titanium dioxide coating substantially boosts the microbial colonization efficiency of silicon carbide, thereby enhancing the overall wastewater purification efficiency in RAS. Full article
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11 pages, 3581 KiB  
Article
All-Fiber Flexible Electrochemical Sensor for Wearable Glucose Monitoring
by Zeyi Tang, Jinming Jian, Mingxin Guo, Shangjian Liu, Shourui Ji, Yilong Li, Houfang Liu, Tianqi Shao, Jian Gao, Yi Yang and Tianling Ren
Sensors 2024, 24(14), 4580; https://doi.org/10.3390/s24144580 (registering DOI) - 15 Jul 2024
Viewed by 135
Abstract
Wearable sensors, specifically microneedle sensors based on electrochemical methods, have expanded extensively with recent technological advances. Today’s wearable electrochemical sensors present specific challenges: they show significant modulus disparities with skin tissue, implying possible discomfort in vivo, especially over extended wear periods or on [...] Read more.
Wearable sensors, specifically microneedle sensors based on electrochemical methods, have expanded extensively with recent technological advances. Today’s wearable electrochemical sensors present specific challenges: they show significant modulus disparities with skin tissue, implying possible discomfort in vivo, especially over extended wear periods or on sensitive skin areas. The sensors, primarily based on polyethylene terephthalate (PET) or polyimide (PI) substrates, might also cause pressure or unease during insertion due to the skin’s irregular deformation. To address these constraints, we developed an innovative, wearable, all-fiber-structured electrochemical sensor. Our composite sensor incorporates polyurethane (PU) fibers prepared via electrospinning as electrode substrates to achieve excellent adaptability. Electrospun PU nanofiber films with gold layers shaped via thermal evaporation are used as base electrodes with exemplary conductivity and electrochemical catalytic attributes. To achieve glucose monitoring, gold nanofibers functionalized by gold nanoflakes (AuNFs) and glucose oxidase (GOx) serve as the working electrode, while Pt nanofibers and Ag/AgCl nanofibers serve as the counter and reference electrode. The acrylamide-sodium alginate double-network hydrogel synthesized on electrospun PU fibers serves as the adhesive and substance-transferring layer between the electrodes. The all-fiber electrochemical sensor is assembled layer-by-layer to form a robust structure. Given the stretchability of PU nanofibers coupled with a high specific surface area, the manufactured porous microneedle glucose sensor exhibits enhanced stretchability, superior sensitivity at 31.94 μA (lg(mM))−1 cm−2, a broad detection range (1–30 mM), and a significantly low detection limit (1 mM, S/N = 3), as well as satisfactory biocompatibility. Therefore, the novel electrochemical microneedle design is well-suited for wearable or even implantable continuous monitoring applications, thereby showing promising significant potential within the global arena of wearable medical technology. Full article
(This article belongs to the Special Issue Wearable and Implantable Electrochemical Sensors)
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20 pages, 6358 KiB  
Article
Investigation of the Effectiveness of Barrier Layers to Inhibit Mutagenic Effects of Recycled LDPE Films, Using a Miniaturized Ames Test and GC-MS Analysis
by Lukas Prielinger, Smarak Bandyopadhyay, Eva Ortner, Martin Novak, Tanja Radusin, Steffen Annfinsen, Nusrat Sharmin, Bernhard Rainer and Marit Kvalvåg Pettersen
Recycling 2024, 9(4), 57; https://doi.org/10.3390/recycling9040057 (registering DOI) - 15 Jul 2024
Viewed by 207
Abstract
To fulfil the European Green Deal targets and implement a circular economy, there is an urgent need to increase recycling rates of packaging materials. However, before recycled materials can be used in food contact applications, they must meet high safety standards. According to [...] Read more.
To fulfil the European Green Deal targets and implement a circular economy, there is an urgent need to increase recycling rates of packaging materials. However, before recycled materials can be used in food contact applications, they must meet high safety standards. According to the European Food Safety Authority (EFSA), a worst-case scenario must be applied and unknown substances must be evaluated as being potentially genotoxic. The Ames test, which detects direct DNA-reactive effects, together with chromatographic analysis is very promising to complement risk assessment. This study aims to evaluate the effectiveness of functional barriers in ten different samples, including virgin and recycled LDPE foils. FT-IR analysis did not show major differences between virgin and recycled films. Light microscopy revealed differences in quality and an increased number of particles. GC-MS analysis detected and quantified 35 substances, including eight unknowns. Using a miniaturized version of the Ames test, four of ten samples tested positive in two individual migrates up to a dilution of 12.5%. All virgin LDPE materials tested negative; however, recycled material F showed an increased mutagenic activity, with an n-fold induction up to 28. Samples with functional barriers lowered migration and reduced mutagenicity. Nonetheless, further investigations are needed to identify possible sources of contamination. Full article
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13 pages, 5640 KiB  
Article
Graphene and Vanadium Dioxide-Based Terahertz Absorber with Switchable Multifunctionality for Band Selection Applications
by Yan Liu, Lingxi Hu and Ming Liu
Nanomaterials 2024, 14(14), 1200; https://doi.org/10.3390/nano14141200 (registering DOI) - 15 Jul 2024
Viewed by 146
Abstract
This study proposes a multifunctional absorber in the terahertz (THz) regime based on vanadium dioxide (VO2) and graphene with either–or band selector applications, which can be realized by electrically and thermally controlling the Fermi energy level of graphene and vanadium dioxide, [...] Read more.
This study proposes a multifunctional absorber in the terahertz (THz) regime based on vanadium dioxide (VO2) and graphene with either–or band selector applications, which can be realized by electrically and thermally controlling the Fermi energy level of graphene and vanadium dioxide, respectively. The broadband absorption can be achieved with absorptance exceeding 90%, when the VO2 film is in the metallic phase and the Fermi energy levels of the upper and lower graphene layers are simultaneously set to 0.6 and 0 eV, respectively. The double narrowband can be realized when the VO2 film is in the insulating phase and the Fermi energy levels in upper and lower graphene layers are set as 0 and 0.8 eV, respectively. By flexibly shifting between the broadband and the double narrowband, the proposed absorber can be used as an either–or band selector, corresponding optional bandwidth from 2.05 to 2.35 THz, and 3.25 to 3.6 THz. Furthermore, single narrowband absorption can be achieved by setting the conductivity of the VO2 film to appropriate values. The proposed absorber can be used in the THz regime in applications such as multifunctional devices, switches, cloaking objects, and band selectors. Full article
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10 pages, 4742 KiB  
Article
Effect of SiO2 Layer Thickness on SiO2/Si3N4 Multilayered Thin Films
by Ziming Huang, Jiaqi Duan, Minghan Li, Yanping Ma and Hong Jiang
Coatings 2024, 14(7), 881; https://doi.org/10.3390/coatings14070881 (registering DOI) - 14 Jul 2024
Viewed by 259
Abstract
Silicon nitride (Si3N4) materials are widely used in the electronics, optoelectronics, and semiconductor industries, with Si3N4 thin films exhibiting high densities, high dielectric constants, good insulation performance, and good thermal and chemical stability. However, direct deposition [...] Read more.
Silicon nitride (Si3N4) materials are widely used in the electronics, optoelectronics, and semiconductor industries, with Si3N4 thin films exhibiting high densities, high dielectric constants, good insulation performance, and good thermal and chemical stability. However, direct deposition of Si3N4 thin films on glass can result in considerable tensile stress and cracking. In this study, magnetron sputtering was used to deposit a Si3N4 thin film on glass, and a silicon dioxide (SiO2) thin film was introduced to reduce the Si3N4 binding force and stress. The effect of the SiO2 layer thickness on the SiO2/Si3N4 multilayered thin film was explored. The results indicated that the introduction of the SiO2 layer could improve the weak adhesion characteristics of Si3N4 thin films. Moreover, sputtering the SiO2 layer to 150 nm resulted in the highest hardness and transmittance of the SiO2/Si3N4 multilayered thin films. The findings of this study lay a solid foundation for the application of Si3N4 thin films on glass. Full article
(This article belongs to the Section Thin Films)
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12 pages, 265 KiB  
Article
Postcards and Emotions: Modernist Architecture in the Films of Pedro Almodóvar and Woody Allen
by Rubén Romero Santos, Ana Mejón, Begoña Herrero Bernal and Carmen Ciller
Arts 2024, 13(4), 119; https://doi.org/10.3390/arts13040119 - 14 Jul 2024
Viewed by 228
Abstract
Modernism has emerged as the preeminent iconic representation of Barcelona. However, the process through which this peculiar style has attained its iconic status is an arduous and multifaceted endeavor. This paper examines the challenges inherent in the categorization and periodization of Modernisme, followed [...] Read more.
Modernism has emerged as the preeminent iconic representation of Barcelona. However, the process through which this peculiar style has attained its iconic status is an arduous and multifaceted endeavor. This paper examines the challenges inherent in the categorization and periodization of Modernisme, followed by a succinct review of its initial filmic representations, culminating in a comprehensive analysis of two films in which Modernisme assumes a pivotal role: All About My Mother (Pedro Almodóvar 1999) and Vicky Cristina Barcelona (Woody Allen 2008). We conclude that Modernisme’s transformation into a cultural brand is largely attributable to the erosion of its ideological component in favor of a touristic and globalizing gaze. Full article
(This article belongs to the Special Issue Arts: Art and Urban Studies)
26 pages, 5339 KiB  
Article
Enhance Ethanol Sensing Performance of Fe-Doped Tetragonal SnO2 Films on Glass Substrate with a Proposed Mathematical Model for Diffusion in Porous Media
by Juan G. Sotelo, Jaime Bonilla-Ríos and José L. Gordillo
Sensors 2024, 24(14), 4560; https://doi.org/10.3390/s24144560 (registering DOI) - 14 Jul 2024
Viewed by 282
Abstract
This research enhances ethanol sensing with Fe-doped tetragonal SnO2 films on glass, improving gas sensor reliability and sensitivity. The primary objective was to improve the sensitivity and operational efficiency of SnO2 sensors through Fe doping. The SnO2 sensors were synthesized [...] Read more.
This research enhances ethanol sensing with Fe-doped tetragonal SnO2 films on glass, improving gas sensor reliability and sensitivity. The primary objective was to improve the sensitivity and operational efficiency of SnO2 sensors through Fe doping. The SnO2 sensors were synthesized using a flexible and adaptable method that allows for precise doping control, with energy-dispersive X-ray spectroscopy (EDX) confirming homogeneous Fe distribution within the SnO2 matrix. A morphological analysis showed a surface structure ideal for gas sensing. The results demonstrated significant improvement in ethanol response (1 to 20 ppm) and lower temperatures compared to undoped SnO2 sensors. The Fe-doped sensors exhibited higher sensitivity, enabling the detection of low ethanol concentrations and showing rapid response and recovery times. These findings suggest that Fe doping enhances the interaction between ethanol molecules and the sensor surface, improving performance. A mathematical model based on diffusion in porous media was employed to further analyze and optimize sensor performance. The model considers the diffusion of ethanol molecules through the porous SnO2 matrix, considering factors such as surface morphology and doping concentration. Additionally, the choice of electrode material plays a crucial role in extending the sensor’s lifespan, highlighting the importance of material selection in sensor design. Full article
(This article belongs to the Special Issue Smart Sensor Systems for Detection of Volatile Organic Compounds)
17 pages, 3294 KiB  
Article
Investigating Cellulose Nanocrystal and Polyvinyl Alcohol Composite Film in Moisture Sensing Application
by Ananya Ghosh, Mahesh Parit and Zhihua Jiang
Polysaccharides 2024, 5(3), 288-304; https://doi.org/10.3390/polysaccharides5030019 (registering DOI) - 14 Jul 2024
Viewed by 201
Abstract
This study focused on utilizing cellulose nanocrystal (CNC)–polyvinyl alcohol (PVA) composite in optical sensor applications to detect high humidity conditions and determine water concentration in ethanol. We focused on the composite’s effectiveness in moisture absorption to demonstrate visual color change. We demonstrated that [...] Read more.
This study focused on utilizing cellulose nanocrystal (CNC)–polyvinyl alcohol (PVA) composite in optical sensor applications to detect high humidity conditions and determine water concentration in ethanol. We focused on the composite’s effectiveness in moisture absorption to demonstrate visual color change. We demonstrated that the different molecular weights of PVA significantly affect CNC’s chiral nematic structure and moisture absorption capability. PVA with molecular weight 88 k–97 k exhibited the disintegration of its chiral nematic structure at 30 wt%, whereas low molecular weight PVA (n~1750) showed no structural disintegration even at 100 wt% concentration when analyzed through UV-Vis spectroscopy. Further, the thermal crosslinking of the CNC-PVA composite showed no significant loss of moisture sensitivity for all molecular weights of the PVA. We observed that the addition of PVA to the sulfated CNC obtained from sulfuric acid hydrolysis did not facilitate moisture absorption significantly. A CNC-PVA sensor was developed which can detect high humidity with 2 hrs. of exposure time. 2,2,6,6-tetramethylpiperidin-1-piperidinyloxy oxidized CNC (TEMPO-CNC) having carboxylic functionality was also used to prepare the CNC-PVA composite films for comparing the effect of functional groups on moisture sensitivity. Finally, we demonstrated a facile method for utilizing the composite as an optical sensor to detect water concentration in ethanol efficiently; thus, it can be used in polar organic solvent dehydration applications. Full article
22 pages, 6964 KiB  
Article
High-Temperature Stirring Pretreatment of Waste Rubber Particles Enhances the Interfacial Bonding and Mechanical Properties of Rubberized Concrete
by Yuan Jing, Chunwei Zhang, Ali Arab, Guangyi Lin and Meng Zhao
Buildings 2024, 14(7), 2162; https://doi.org/10.3390/buildings14072162 - 14 Jul 2024
Viewed by 269
Abstract
This paper innovatively proposes a method of 180 °C high-temperature stirring pretreatment for waste rubber particles and compares this method with untreated, NaOH-treated, and silane coupling agent KH570-treated waste rubber particles. Fourier-transform infrared spectroscopy, X-ray diffraction analysis, water contact angle measurement, scanning electron [...] Read more.
This paper innovatively proposes a method of 180 °C high-temperature stirring pretreatment for waste rubber particles and compares this method with untreated, NaOH-treated, and silane coupling agent KH570-treated waste rubber particles. Fourier-transform infrared spectroscopy, X-ray diffraction analysis, water contact angle measurement, scanning electron microscopy, and energy-dispersive X-ray study are used to investigate the effects and mechanisms of different pretreatment methods on waste rubber particles. The results indicate that compared to NaOH-treated and KH570-treated waste rubber particles, the 180 °C high-temperature-stirred pretreated waste rubber particles show significantly improved cleanliness and form a hard oxide film. The study also investigates the effects of different pretreatment methods on the mechanical properties and interface binding performance of rubber concrete made from pretreated waste rubber particles. The results demonstrate that rubber concrete prepared using 180 °C high-temperature-stirred pretreated waste rubber particles substituting 20% fine aggregate exhibits the best mechanical properties and interface bonding performance. The compressive strength recovery rates after 7 and 28 days are 41.6% and 37.3%, respectively; the split tensile strength recovery rates are 47.3% and 60.6%; the axial compressive strength recovery rates are 34.1% and 18.8%; and the static compression moduli of elasticity recovery rates are 46.8% and 26.3%. High-temperature stirring pretreatment of waste rubber particles is simple to operate and suitable for scaled production. Its pretreatment effect is superior to those of the KH570 and NaOH methods, providing a reference value for the scalable application of waste rubber particles as a substitute for fine aggregate in rubber concrete. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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13 pages, 5595 KiB  
Article
Engineering of Silane–Pyrrolidone Nano/Microparticles and Anti-Fogging Thin Coatings
by Natalie Mounayer and Shlomo Margel
Polymers 2024, 16(14), 2013; https://doi.org/10.3390/polym16142013 - 14 Jul 2024
Viewed by 243
Abstract
Polyvinylpyrrolidone (PVP) exhibits remarkable qualities; owing to the strong affinity for water of its pyrrolidone group, which enhances compatibility with aqueous systems, it is effective for stabilizing, binding, or carrying food, drugs, and cosmetics. However, coating the surface of polymeric films with PVP [...] Read more.
Polyvinylpyrrolidone (PVP) exhibits remarkable qualities; owing to the strong affinity for water of its pyrrolidone group, which enhances compatibility with aqueous systems, it is effective for stabilizing, binding, or carrying food, drugs, and cosmetics. However, coating the surface of polymeric films with PVP is not practical, as the coatings dissolve easily in water and ethanol. Poly(silane–pyrrolidone) nano/microparticles were prepared by combining addition polymerization of methacryloxypropyltriethoxysilane and N-vinylpyrrolidone, followed by step-growth Stöber polymerization of the formed silane–pyrrolidone monomer. The silane–pyrrolidone monomeric solution was spread on oxidized polyethylene films with a Mayer rod and polymerized to form siloxane (Si-O-Si) self-cross-linked durable anti-fog thin coatings with pyrrolidone groups exposed on the outer surface. The coatings exhibited similar wetting properties to PVP with significantly greater stability. The particles and coatings were characterized by microscopy, contact angle measurements, and spectroscopy, and tested using hot fog. Excellent anti-fogging activity was found. Full article
(This article belongs to the Section Polymer Membranes and Films)
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21 pages, 6113 KiB  
Article
Exploring Heterointerface Characteristics and Charge-Storage Dynamics in ALD-Developed Ultra-Thin TiO2-In2O3/Au Heterojunctions
by Mohammad Karbalaei Akbari, Nasrin Siraj Lopa and Serge Zhuiykov
Coatings 2024, 14(7), 880; https://doi.org/10.3390/coatings14070880 (registering DOI) - 14 Jul 2024
Viewed by 220
Abstract
Directional ionic migration in ultra-thin metal-oxide semiconductors under applied electric fields is a key mechanism for developing various electronic nanodevices. However, understanding charge transfer dynamics is challenging due to rapid ionic migration and uncontrolled charge transfer, which can reduce the functionality of microelectronic [...] Read more.
Directional ionic migration in ultra-thin metal-oxide semiconductors under applied electric fields is a key mechanism for developing various electronic nanodevices. However, understanding charge transfer dynamics is challenging due to rapid ionic migration and uncontrolled charge transfer, which can reduce the functionality of microelectronic devices. This research investigates the supercapacitive-coupled memristive characteristics of ultra-thin heterostructured metal-oxide semiconductor films at TiO2-In2O3/Au Schottky junctions. Using atomic layer deposition (ALD), we nano-engineered In2O3/Au-based metal/semiconductor heterointerfaces. TEM studies followed by XPS elemental analysis revealed the chemical and structural characteristics of the heterointerfaces. Subsequent AFM studies of the hybrid heterointerfaces demonstrated supercapacitor-like behavior in nanometer-thick TiO2-In2O3/Au junctions, resembling ultra-thin supercapacitors, pseudocapacitors, and nanobatteries. The highest specific capacitance of 2.6 × 104 F.g−1 was measured in the TiO2-In2O3/Au junctions with an amorphous In2O3 electron gate. Additionally, we examined the impact of crystallization, finding that thermal annealing led to the formation of crystalline In2O3 films with higher oxygen vacancy content at TiO2-In2O3 heterointerfaces. This crystallization process resulted in the evolution of non-zero I-V hysteresis loops into zero I-V hysteresis loops with supercapacitive-coupled memristive characteristics. This research provides a platform for understanding and designing adjustable ultra-thin Schottky junctions with versatile electronic properties. Full article
(This article belongs to the Special Issue Advanced Films and Coatings Based on Atomic Layer Deposition)
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16 pages, 3536 KiB  
Article
The Design and Experimentation of a Differential Grain Moisture Detection Device for a Combined Harvester
by Zheng Liu, Tengxiang Yang, Panpan Li, Jin Wang, Jinshan Xu and Chengqian Jin
Sensors 2024, 24(14), 4551; https://doi.org/10.3390/s24144551 (registering DOI) - 13 Jul 2024
Viewed by 424
Abstract
To conveniently implement the online detection of grain moisture in combined harvesters and the address the influence of the no-load measurement baseline, thereby enhancing detection accuracy and measurement continuity, this study developed a differential grain moisture detection device. For its convenient installation and [...] Read more.
To conveniently implement the online detection of grain moisture in combined harvesters and the address the influence of the no-load measurement baseline, thereby enhancing detection accuracy and measurement continuity, this study developed a differential grain moisture detection device. For its convenient installation and integration on combined harvesters, a single-pole plate measurement element with a 1.6 mm thick epoxy resin coated with a 2-ounce copper film was designed, and a grain moisture detection device was constructed based on the STM32F103 microprocessor (STMicroelectronics International NV, Geneva, Switzerland). To enhance the device’s interference resistance, a differential amplification measurement circuit integrated with high-frequency excitation was designed using a reference capacitance. To improve the resolution of the measurement circuit, Malab simulations were conducted at different excitation frequencies, ultimately selecting 30 kHz as the system’s excitation signal frequency. To validate the effectiveness of the measurement circuit, validity tests were performed on the constructed sensor, which showed that the sensor’s measurement voltage could effectively distinguish the moisture levels in grains, with a determination coefficient (R²) reaching 0.9978. To address the errors in moisture measurement caused by changes in grain temperature, an interaction experiment of the effect of moisture content and temperature on the measurement voltage was conducted using an integrated temperature sensor, resulting in the construction of a moisture content calculation model. Both the indoor static detection and field testing of the moisture detection device were conducted, indicating that the maximum average error in static measurements was 0.3%, with a maximum relative error of 0.47%, and the average relative error in field tests was ≤0.4%. Full article
(This article belongs to the Section Smart Agriculture)
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15 pages, 4184 KiB  
Article
Numerical Simulations and Experimental Validation of Squeeze Film Dampers for Aircraft Jet Engines
by Markus Golek, Jakob Gleichner, Ioannis Chatzisavvas, Lukas Kohlmann, Marcus Schmidt, Peter Reinke and Adrian Rienäcker
Lubricants 2024, 12(7), 253; https://doi.org/10.3390/lubricants12070253 - 13 Jul 2024
Viewed by 222
Abstract
Squeeze film dampers are used to reduce vibration in aircraft jet engines supported by rolling element bearings. The underlying physics of the squeeze film dampers has been studied extensively over the past 50 years. However, the research on the SFDs is still ongoing [...] Read more.
Squeeze film dampers are used to reduce vibration in aircraft jet engines supported by rolling element bearings. The underlying physics of the squeeze film dampers has been studied extensively over the past 50 years. However, the research on the SFDs is still ongoing due to the complexity of modeling of several effects such as fluid inertia and the modeling of the piston rings, which are often used to seal SFDs. In this work, a special experimental setup has been designed to validate the numerical models of SFDs. This experimental setup can be used with various SFD geometries (including piston ring seals) and simulate almost all conditions that may occur in an aircraft jet engine. This work also focuses on the inertia forces of the fluid. The hydrodynamic pressure distribution of a detailed 3D-CFD model is compared with the solution of the Reynolds equation including inertia effects. Finally, the simulation results are compared with experimental data and good agreement is observed. Full article
(This article belongs to the Special Issue Tribology in Germany: Latest Research and Development)
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